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Journal Articles

Decomposition behavior of gaseous ruthenium tetroxide under atmospheric conditions assuming evaporation to dryness accident of high-level liquid waste

Yoshida, Naoki; Ono, Takuya; Yoshida, Ryoichiro; Amano, Yuki; Abe, Hitoshi

Journal of Nuclear Science and Technology, 57(11), p.1256 - 1264, 2020/11

https://doi.org/10.1080/00223131.2020.1780991
 Times Cited Count：9 Percentile：74.38(Nuclear Science & Technology)

Emphasis has been placed on the behavior of ruthenium (Ru) in the evaporation to dryness accident due to the loss of cooling functions (EDLCF) of high-level liquid waste in fuel reprocessing plants. It is because Ru would form volatile compounds such as ruthenium tetroxide (RuO$$_{4}$$) and could be released into the environment with other coexisting gasses such as nitric acid (HNO$$_{3}$$), water (H$$_{2}$$O). To contribute to the safety evaluation of this accident, we experimentally evaluated the decomposition and chemical change behavior of the gaseous RuO$$_{4}$$ (RuO$$_{4}$$(g)) under the various atmospheric conditions: temperature and composition of coexisting gasses. As a result, the behavior of the RuO$$_{4}$$(g) was diverse depending on the atmospheric conditions. In the experiments with the dry air or H$$_{2}$$O vapor, decomposition of RuO$$_{4}$$(g) was observed. In the experiment with the mixed gas which containing HNO$$_{3}$$, almost no decomposition of the RuO$$_{4}$$(g) was observed, and chemical form of the RuO$$_{4}$$(g) was retained.

Journal Articles

Chemical behavior of platinum group compounds in the vitrification process condition

Nagai, Takayuki; Akiyama, Daisuke*; Sato, Nobuaki*; Sasage, Kenichi

Busshitsu, Debaisu Ryoiki Kyodo Kenkyu Kyoten Kenkyu Seika Hokokusho (Heisei-28-Nendo) (CD-ROM), 1 Pages, 2017/03

no abstracts in English

Journal Articles

Investigation of ruthenium compounds in the vitrification process condition

Nagai, Takayuki; Sato, Nobuaki*; Sasage, Kenichi

Busshitsu, Debaisu Ryoiki Kyodo Kenkyu Kyoten Kenkyu Seika Hokokusho (Heisei-27-Nendo) (CD-ROM), 2 Pages, 2016/03

no abstracts in English

JAEA Reports

None

*; Mano, Tadashi*;

PNC TN1410 91-034, 10 Pages, 1991/05

PNC-TN1410-91-034.pdf:0.12MB

no abstracts in English

Oral presentation

Investigation of the chemical form of ruthenium compounds in the vitrification process, 3; Reactions of lanthanide nitrates and ruthenium nitrates included in a liquid waste

Nagai, Takayuki; Sasage, Kenichi; Oyama, Koichi; Sato, Nobuaki*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*

no journal, , 

no abstracts in English

Oral presentation

Investigation of the chemical form of ruthenium compounds in the vitrification process, 4; RuO$$_{2}$$ generation by reaction with Ru-La-Na mix nitrates and raw materials for vitrification

Nagai, Takayuki; Kobayashi, Hidekazu; Okamoto, Yoshihiro; Sato, Nobuaki*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*; Seki, Katsumi*

no journal, , 

It is thought that a generated ruthenium compound grows from a high level radioactive liquid waste into RuO$$_{2}$$ crystal by reacting to raw materials for the vitrification process. In this study, the generation reaction to RuO$$_{2}$$ was confirmed by heating Ru-La-Na mix nitrates and the raw materials.

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